36 0 obj <> endobj Such materials are peer reviewed and may be re‐organized for online delivery, but are not copy‐edited or typeset. if (d.getElementById(id)) return; Ammonia borane (NH 3 BH 3, abbreviated hereafter as AB), ... Hybridization of various rational selected hydrogen storage species has been proved to be a practicable strategy to improve the thermodynamics of the hydrogen storage system. fjs.parentNode.insertBefore(js, fjs); You do not have JavaScript enabled. 0000001598 00000 n ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Thermodynamics study of hydrogen storage materials. You have to login with your ACS ID befor you can login with your Mendeley account. Hydrogen is frequently discussed as a clean energy in the future without pollution. There four sp3 hybrid orbitals of nitrogen atom of  ammonia is formed by the overlapping of three half filled orbitals of  Nitrogen atom with s-orbital of 3 hydrogen atoms. The bond angle is 104.50. Further, phenylacetylene semi‐hydrogenation with AB over Pd@UiO‐66 (Hf) furnished styrene selectivity as high as 93.2 % at ∼100 % conversion mostly due to the regulated phenylacetylene diffusion through UiO‐66(Hf) shell. 0000009354 00000 n One can also use H3N as the molecular formula of Ammonia, and the molecular weight of the component is 17.031 g/mol. that the correct acknowledgement is given with the reproduced material. Information about how to use the RightsLink permission system can be found at 0000010778 00000 n These four sp3 hybrid orbitals form sigma bond with singly filled s-orbital of H- atom and four sigma bonds are formed. 0000124770 00000 n Ammonia borane (AB), having a high hydrogen density of 19.6 wt %, has attracted much attention as a promising chemical hydrogen storage material. If you do not receive an email within 10 minutes, your email address may not be registered, AB–MH (Ammonia Borane–Metal Hydride) composites: systematic understanding of dehydrogenation properties. Thermodynamics study of hydrogen storage materials. Yoshitsugu Kojima, Hiroki Miyaoka, Takayuki Ichikawa. The hypothetical overlap of two of the 2p orbitals on an oxygen atom (red) with the 1s orbitals of … Kun Wang, Jian-Guo Zhang, Tian-Tian Man, Man Wu, Chun-Chun Chen. Baicheng Weng, Zhu Wu, Zhilin Li, Hui Yang. Krishna Kharel, Radhika Gangineni, Özge Günaydın-Şen. 0000003318 00000 n 0000134212 00000 n Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts. Unlimited viewing of the article PDF and any associated supplements and figures. H�tT�n�0��+x$k�7��� A@�QOA�MJ,)���.I�q��%�ܝ��Z����/����B[��%(I�Q�A�)��.�u-1��B��F�W\;n�� Hydrogen generation from hydrolysis of NH3BH3/MH (M=Li, Na) binary hydrides. H. Miao, K. Ma, H. Zhu, K. Yin, Y. Zhang and Y. Cui, School of Chemistry and Materials Engineering, Fuyang Normal University, Anhui Provincial Key Laboratory for Degradation and Monitoring of Pollution of the Environment, Fuyang, China, Creative Commons Attribution 3.0 Unported 0000124683 00000 n to access the full features of the site or access our. Users are Copyright © 2020 Elsevier B.V. or its licensors or contributors. -���8M�M�VE�U_,���\���Ѷ:F�Rs��љ�>OSxi*�f���g\�ť�� �U�*���0����&VZ�h�J �v�DV4������V���$��2���a�� ���_��/�d�Cx�O�;�[�x��(��R�L*���1C�C�%����M���"��(8���ⶤ�Y0H9�,� �ƤM��H��,X��KMw��=Я;X���8Xzϰ�t|b�������l�N��Z&h�-��Ε�߄����[�9��h�聣�;��hM����z������H��Y0���>="M�1��aI"�)�����G|�.C��0u͖����If�*;ف���\�W�O�$Ha�4�P��a?��mX����:5�nȸ!��~��\�S3��INb�L�{�J\d'�E��4�1���ԭs�9���G�" It is the simplest boron-nitrogen compound. Kun Wang, Jianguo Zhang, Tonglai Zhang. Theoretical study of the structure and dehydrogenation mechanism of sodium hydrazinidoborane.


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